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The pressure vessel in a boiler is usually made of steel (or alloy steel), or historically of wrought iron. Stainless steel is virtually prohibited (by the ASME Boiler Code) for use in wetted parts of modern boilers, but is used often in superheater sections that will not be exposed to liquid boiler water. In live steam models, copper or brass is often used because it is more easily fabricated in smaller size boilers. Historically, copper was often used for fireboxes (particularly for steam locomotives), because of its better formability and higher thermal conductivity; however, in more recent times, the high price of copper often makes this an uneconomic choice and cheaper substitutes (such as steel) are used instead. For much of the Victorian "age of steam", the only material used for boilermaking was the highest grade of wrought iron, with assembly by rivetting. This iron was often obtained from specialist ironworks, such as at Cleator Moor (UK), noted for the high quality of their rolled plate and its suitability for high-reliability use in critical applications, such as high-pressure boilers. In the 20th century, design practice instead moved towards the use of steel, which is stronger and cheaper, with welded construction, which is quicker and requires less labour. Cast iron may be used for the heating vessel of domestic water heaters. Although such heaters are usually termed "boilers", their purpose is usually to produce hot water, not steam, and so they run at low pressure and try to avoid actual boiling. The brittleness of cast iron makes it impractical for high pressure steam boilers.

Fuel

The source of heat for a boiler is combustion of any of several fuels, such as wood, coal, oil, or natural gas. Electric steam boilers use resistance- or immersion-type heating elements. Nuclear fission is also used as a heat source for generating steam. Heat recovery steam generators (HRSGs) use the heat rejected from other processes such as gas turbines.

Safety

Historically, boilers were a source of many serious injuries and property destruction due to poorly understood engineering principles. Thin and brittle metal shells can rupture, while poorly welded or riveted seams could open up, leading to a violent eruption of the pressurized steam. Collapsed or dislodged boiler tubes could also spray scalding-hot steam and smoke out of the air intake and firing chute, injuring the firemen that loaded coal into the fire chamber. Extremely large boilers providing hundreds of horsepower to operate factories could demolish entire buildings.

A boiler that has a loss of feed water and is permitted to boil dry can be extremely dangerous. If feed water is then sent into the empty boiler, the small cascade of incoming water instantly boils on contact with the superheated metal shell and leads to a violent explosion that cannot be controlled even by safety steam valves. Draining of the boiler could also occur if a leak occurred in the steam supply lines that was larger than the make-up water supply could replace. The Hartford Loop was invented in 1919 by the Hartford Steam Boiler and Insurance Company as a method to help prevent this condition from occurring, and thereby reduce their insurance claims.

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